The Bachelorette Season 6 Episode 1 (The Bachelorette s06e01) airs on Monday, May 24th 2010 at 09:00 pm via ABC.
Here is summary for The Bachelorette Season 6 Episode 1 :

Bachelorette Ali Fedotowsky, who chose her job over Bachelor Jake Pavelka, gets to do the snubbing this time, sifting through 25 guys, eight of whom won’t make it beyond the Season 6 premiere.

Few hours after original series aired on TV, online streaming video for The Bachelorette Season 6 Episode 1 usually available on Net and of course, if video available, as soon as possible will show you where you can watch this episode for free.