The Good Wife Season 1 Episode 22 (The Good Wife s01e22) with title “Hybristophilia” airs on Tuesday, May 18th 2010 at 10:00 pm via CBS.
Here is summary for The Good Wife Season 1 Episode 22 :

Eli Gold works on getting Peter’s charges dropped, and Alicia defends Colin Sweeney, a client and accused wife killer, who claims self defense after she finds him handcuffed to a dead woman.

Few hours after original series aired on TV, online streaming video for The Good Wife Season 1 Episode 22 usually available on Net and of course, if video available, as soon as possible will show you where you can watch this episode for free.