100 Questions Season 1 Episode 5 (100 Questions s01e05) with title “Wayne?” airs on Thursday, June 24th 2010 at 08:30 pm via NBC Network.
Here is summary for 100 Questions Episode 5 :

Charlotte recalls how she met Wayne. Elsewhere Leslie learns that her ex is remarrying. Meanwhile, Wayne confides that his father has cut him off from his money.

Few hours after original series aired on TV, online streaming video for 100 Questions Season 1 Episode 5 usually available on Net and of course, if video available, as soon as possiblewill show you where you can watch this episode for free.