Gossip Girl Season 4 Episode 3 (Gossip Girl s04e03) with title “The Undergraduates” aired on Monday, September 27th 2010 at 09:00 pm via CW Network.
Here is summary for Gossip Girl Season 4 Episode 3 :

Blair begins her studies at Columbia and seeks entry into a prestigious social club. Elsewhere, Serena develops a distrust of Juliet, who she suspects is deliberately wreaking havoc on her life; and Rufus’ concerns about Dan compel him to take action.

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